Cross-coupling of organic fluorides with allenes: a silyl-radical-relay pathway for the construction of α-alkynyl-substituted all-carbon quaternary centres-Reference-Cited by-同舟云学术

Cross-coupling of organic fluorides with allenes: a silyl-radical-relay pathway for the construction of α-alkynyl-substituted all-carbon quaternary centres

Published:2024 Issue:14 Volume:15 Page:5113-5122
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhou Jun¹^ORCID,Zhao Zhengyu¹,Mori Soichiro²,Yamamoto Katsuhiro²^ORCID,Shibata Norio¹²^ORCID

Affiliation:

1. Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan

2. Department of Life Science and Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan

Abstract

Cross-coupling of organic fluorides with allenes via radical rearrangement to afford all-carbon quaternary centres mediated by silylboronate/potassium tert-butoxide is disclosed.

Funder

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06617G

Reference105 articles.

1. Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric synthesis of all-carbon quaternary stereocenters

2. Catalytic enantioselective synthesis of quaternary carbon stereocentres

3. Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

4. Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

5. All-carbon quaternary centers in natural products and medicinal chemistry: recent advances

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