The strongest CO binding and the highest C–O stretching frequency-Reference-Cited by-同舟云学术

The strongest CO binding and the highest C–O stretching frequency

Published:2017 Issue:3 Volume:19 Page:2286-2293
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Saha Ranajit¹²³,Pan Sudip⁴⁵⁶⁷⁸^ORCID,Frenking Gernot⁹¹⁰¹¹¹²,Chattaraj Pratim K.¹²³,Merino Gabriel⁴⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry and Centre for Theoretical Studies

2. Indian Institute of Technology Kharagpur

3. India

4. Departamento de Física Aplicada

5. Centro de Investigación y de Estudios Avanzados

6. Unidad Mérida

7. Mérida

8. Mexico

9. Fachbereich Chemie

10. Philipps-Universität Marburg Hans-Meerwein-Straße

11. 35032 Marburg

12. Germany

Abstract

OCBeSO₄ has the highest C–O stretching frequency among the neutral carbonyls which is a consequence of the largest OC→BeSO₄ σ-donation along with the smallest OC←BeSO₄ π-back-donation.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP06824C

Reference61 articles.

1. Hydrides of Boron. VII. Evidence of the Transitory Existence of Borine (BH3): Borine Carbonyl and Borine Trimethylammine

2. Carbonyl Compounds of Boron and Their Isomers

3. Carbonyltris(trifluoromethyl)borane, (CF3)3BCO, An Unusual Boron Carbonyl This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie (D.F.G), Merck KGaA, Darmstadt, and the Heinrich Hertz Stiftung (Grant to F.A.)

4. Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCOSynthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase, and Solid State Structure

5. OCBBCO: A Neutral Molecule with Some Boron−Boron Triple Bond Character

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