Triple bonding between beryllium and nitrogen in HNBeCO-Reference-Cited by-同舟云学术

Triple bonding between beryllium and nitrogen in HNBeCO

Published:2022 Issue:61 Volume:58 Page:8532-8535
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Lina¹,Pan Sudip²^ORCID,Wang Guanjun¹^ORCID,Zeng Xiaoqing¹^ORCID,Zhou Mingfei¹^ORCID,Frenking Gernot²³⁴^ORCID

Affiliation:

1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai, 200438, China

2. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, D-35043, Marburg, Germany

3. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 211816, China

4. Donostia International Physics Center (DIPC), P.K. 1072, 20080 Donostia, Euskadi, Spain

Abstract

HNBeCO is generated in a neon matrix and identified via vibrational spectroscopy. It possesses an unprecedented triple bond, consisting of two π-bonds and a dative σ-bond, with the former bonds being much stronger than the latter bond.

Funder

National Natural Science Foundation of China

Nanjing Tech University

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02969C

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