Structurally diverse arene-fused ten-membered lactams accessed via hydrolytic imidazoline ring expansion

Author:

Sapegin Alexander1234,Osipyan Angelina1234,Krasavin Mikhail1234ORCID

Affiliation:

1. Institute of Chemistry

2. Saint Petersburg State University

3. Peterhof 198504

4. Russia

Abstract

A facile approach to hitherto unknown ten-membered ring systems via a hydrolytic imidazoline ring expansion (HIRE) is described. Medium-sized rings are scarce in the contemporary medicinal chemistry toolbox. The new HIRE strategy broadens the arsenal of synthetic methods to obtain such scaffolds.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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