Catalytic formal cycloadditions between anhydrides and ketones: excellent enantio and diastereocontrol, controllable decarboxylation and the formation of adjacent quaternary stereocentres-Reference-Cited by-同舟云学术

Catalytic formal cycloadditions between anhydrides and ketones: excellent enantio and diastereocontrol, controllable decarboxylation and the formation of adjacent quaternary stereocentres

Published:2016 Issue:11 Volume:14 Page:3040-3046
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Cornaggia Claudio¹²³⁴⁵,Gundala Sivaji¹²³⁴⁵,Manoni Francesco¹²³⁴⁵,Gopalasetty Nagaraju¹²³⁴⁵,Connon Stephen J.¹²³⁴⁵

Affiliation:

1. Trinity Biomedical Sciences Institute

2. School of Chemistry

3. The University of Dublin

4. Trinity College

5. Dublin 2, Ireland

Abstract

It has been shown for the first time that enolisable anhydrides can participate in highly efficient and diastereo/enantioselective additions to activated ketones.

Funder

European Research Council

Science Foundation Ireland

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00089D

Reference34 articles.

1. Ueber das Phenyl-Butyrolacton und die Phenyl-Paraconsäure

2. XI.—On the formation of coumarin and of cinnamic and of other analogous acids from the aromatic aldehydes