Structure and emission properties of dinuclear copper(i) complexes with pyridyltriazole

Author:

Gusev Alexey1ORCID,Kiskin Mikhail2,Braga Elena1,Zamnius Ekaterina1,Kryukova Mariya3,Karaush-Karmazin Nataliya4ORCID,Baryshnikov Glib45,Minaev Boris4ORCID,Linert Wolfgang6

Affiliation:

1. V.I. Vernadsky Crimean Federal University, Simferopol, 295007, Crimea

2. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

3. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg, Russia

4. Department of Chemistry and Nanomaterials Science, Bohdan Khmelnytsky National University, 18031 Cherkasy, Ukraine

5. Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, SE-60174 Norrköping, Sweden

6. Institute of Applied Physics, Vienna University of Technology, Wiedner Hauptstraße 8-10, 1040 Vienna, Austria

Abstract

New highly emissive copper(i) complexes based on 3/4-pyridyltriazole have been synthesized and fully characterized. Photophysical properties and the mechanism of photo- and mechanochromic and excitation dependent luminescence are discussed.

Funder

Russian Science Foundation

Ministry of Education and Science of Ukraine

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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