Surface modification with a fluorinated N-heterocyclic carbene on Au: effect on contact resistance in organic field-effect transistors

Author:

Wang Zhifang12,Das Mowpriya3,Gutheil Christian3,Osthues Helena4ORCID,Strieth-Kalthoff Felix3ORCID,Timmer Alexander5,Doltsinis Nikos L.4ORCID,Wang Wenchong2ORCID,Chi Lifeng12ORCID,Glorius Frank3ORCID

Affiliation:

1. Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, 199 Ren'ai Road, Suzhou, 215123, Jiangsu, P. R. China

2. Westfälische Wilhelms-Universität Münster, Physikalisches Institut and Center for Nanotechnology (CeNTech), Wilhelm-Klemm-Straße 10, 48149 Münster, Germany

3. Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstraße 36, 48149 Münster, Germany

4. Westfälische Wilhelms-Universität Münster, Institute for Solid State Theory and Center for Multiscale Theory and Computation, Wilhelm-Klemm-Straße 10, 48149 Münster, Germany

5. NanoAnalytics GmbH, Heisenbergstraße 40, 48149 Münster, Germany

Abstract

A fluorinated N-heterocyclic carbene is chemically bonded to Au and employed as a surface modifier to improve contact between electrodes and semiconductors in organic field-effect transistors, showing a significant improvement in device performance.

Funder

National Natural Science Foundation of China

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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