Bi- and trinuclear coinage metal complexes of a PNNP ligand featuring metallophilic interactions and an unusual charge separation-Reference-Cited by-同舟云学术

Bi- and trinuclear coinage metal complexes of a PNNP ligand featuring metallophilic interactions and an unusual charge separation

Published:2021 Issue:38 Volume:50 Page:13412-13420
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dahlen Milena¹,Kehry Max²^ORCID,Lebedkin Sergei³,Kappes Manfred M.²³,Klopper Wim²³^ORCID,Roesky Peter W.¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany

2. Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany

3. Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

Homometallic bi- and trinuclear complexes of Cu, Ag and Au ligated by a tetradentate PNNP ligand are shown. Photoluminescence and theoretical studies revealed a MLCT character upon UV excitation and complemented this work.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02226A

Reference92 articles.

1. Heteronuclear Metal−Metal Contacts between Gold( I ) and Group‐11, ‐12, and ‐13 Centers

2. Heteropolynuclear Gold Complexes with Metallophilic Interactions: Modulation of the Luminescent Properties

3. Predicted ligand dependence of the Au(I)…Au(I) attraction in (XAuPH3)2

4. A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10coinage metals

5. Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d10⋯d10, d10⋯d8, d8⋯d8) metal ions [M⋯M′ M = Hg(ii) and Pd(ii) and M′ = Cu(i), Ag(i), Au(i), and Pd(ii)]

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