Cooperativity in luminescent heterobimetallic diphosphine-β-diketiminate complexes-Reference-Cited by-同舟云学术

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Cooperativity in luminescent heterobimetallic diphosphine-β-diketiminate complexes

Published:2024 Issue:3 Volume:11 Page:853-862
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Krätschmer Frederic¹,Sun Xiaofei¹^ORCID,Frick David¹,Zovko Christina¹,Klopper Wim²,Roesky Peter W.¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany

2. Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany

Abstract

A PNNP ligand was used for the synthesis of luminescent bimetallic complexes, featuring the combination of group 11 and 12 metals. The cooperativity of the metal ions in close spatial proximity led to drastic changes in the photophysical properties.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D3QI01740K

Reference63 articles.

1. Very Large Cooperative Effects in Heterobimetallic Titanium-Chromium Catalysts for Ethylene Polymerization/Copolymerization

2. Photocrystallographic Observation of Halide-Bridged Intermediates in Halogen Photoeliminations

3. Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence

4. Metal-metal interactions in binuclear complexes exhibiting mixed valency; molecular wires and switches

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