Fluorenylporphyrins functionalized by electrochromic ruthenium units as redox-triggered fluorescence switches

Author:

Zhang Xu12345,Abid Seifallah12345,Shi Limiao12345,Williams J. A. Gareth6789ORCID,Fox Mark A.6789ORCID,Miomandre Fabien10111213ORCID,Tourbillon Clarisse10111213,Audibert Jean-Frédéric10111213,Mongin Olivier12345ORCID,Paul Frédéric12345ORCID,Paul-Roth Christine O.12345ORCID

Affiliation:

1. Univ Rennes

2. INSA Rennes

3. CNRS

4. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226

5. F-35000 Rennes

6. Department of Chemistry

7. Durham University

8. Durham

9. U.K

10. PPSM, CNRS

11. Ecole normale supérieure Paris-Saclay

12. 94235 Cachan

13. France

Abstract

The electrofluorochromic behaviour of two ruthenium-appended porphyrin dyads has been investigated. Differences in response according to the nature of the interposed aryl linker are rationalised with the aid of electrochemistry and TD-DFT calculations.

Funder

Centre National de la Recherche Scientifique

China Scholarship Council

Ministère de l’Enseignement Supérieur et de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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