New donor–acceptor conjugates based on a trifluorenylporphyrin linked to a redox–switchable ruthenium unit-Reference-Cited by-同舟云学术

New donor–acceptor conjugates based on a trifluorenylporphyrin linked to a redox–switchable ruthenium unit

Published:2015 Issue:20 Volume:44 Page:9470-9485
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Merhi Areej¹²³⁴⁵,Zhang Xu¹²³⁴⁵,Yao Dandan¹²³⁴⁵,Drouet Samuel¹²³⁴,Mongin Olivier¹²³⁴,Paul Frédéric¹²³⁴,Williams J. A. Gareth⁶⁷⁸⁹,Fox Mark A.⁶⁷⁸⁹^ORCID,Paul-Roth Christine O.¹²³⁴⁵

Affiliation:

1. Institut des Sciences Chimiques de Rennes

2. ISCR-UMR CNRS 6226

3. 35042 Rennes Cedex

4. France

5. Institut National des Sciences Appliquées

6. Department of Chemistry

7. Durham University

8. Durham

9. UK

Abstract

Spectroelectrochemical studies show four accessible redox states on dyad 3 with the first oxidation process taking place at the Ru(ii) centre and the second oxidation and first reduction processes at the porphyrin centre.

Funder

Engineering and Physical Sciences Research Council

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00348B

Reference80 articles.

1. Optical limiting performance of meso-tetraferrocenyl porphyrin and its metal derivatives

2. Interpretation of the UV−vis Spectra of themeso(Ferrocenyl)-Containing Porphyrins using a TDDFT Approach: Is Gouterman’s Classic Four-Orbital Model Still in Play?