Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate
Author:
Affiliation:
1. Henan Key Laboratory of Polyoxometalate Chemistry
2. Institute of Molecular and Crystal Engineering
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng 475004
Abstract
A monomeric trinickel(ii)-substituted phosphotungstate [H9P2W15O62Ni3]9− ion is stabilized by grafting three {Re(CO)3} organometallic groups on the surface of a trinickel cluster for the first time. The resulting polyanions [P2W15O56Ni3(H2O)3(μ3-OH)3(Re(CO)3)3]6− stacked along the a-axis to form a wavy line.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00138C
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