Author:
Zhao Yanxin,Sun Xiaopeng,Ji Yanfang,Kong Hui,Chen Shumin,Ma Pengtao,Niu Jingyang,Wang Jingping
Abstract
A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH4{Mn4[PrMo12O42]}·18H2O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo12O42} has formed 3D frameworks via the {MnO6} linker. The excitation of compound 1 in solid state at 375 nm displays red emission. Moreover, variable temperature magnetic susceptibility measurements indicate that the magnetic behavior in compound 1 is dominated by antiferromagnetic interactions.
Funder
National Natural Science Foundation of China
Cited by
4 articles.
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