Interaction of Nd(iii) and Cm(iii) with borate in dilute to concentrated alkaline NaCl, MgCl2 and CaCl2 solutions: solubility and TRLFS studies

Author:

Hinz Katja1234,Altmaier Marcus1234,Gaona Xavier1234,Rabung Thomas1234,Schild Dieter1234,Richmann Michael5678,Reed Donald T.5678,Alekseev Evgeny V.91011412,Geckeis Horst1234

Affiliation:

1. Institute for Nuclear Waste Disposal

2. Karlsruhe Institute of Technology

3. 76021 Karlsruhe

4. Germany

5. Los Alamos National Laboratory

6. Repository Science and Operations

7. Carlsbad

8. USA

9. Institute of Energy and Climate Research (IEK-6)

10. Forschungszentrum Jülich

11. 52428 Jülich

12. Institut für Kristallographie

Abstract

Interaction of Ln(iii) and An(iii) with borate impacts radionuclide solubility and speciation in saline aqueous solutions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference56 articles.

1. M. Borkowski , J.Garner, J.-F.Lucchini, D.T.Reed and M. K.Richmann, Appendix SOTERM-2009 Actinide Chemistry Source Term LA-UR-13-24559 United States10.2172/1084512Tue Oct 01 11:10:19 EDT 2013LANLEnglish, 2013

2. Long-term cement corrosion in chloride-rich solutions relevant to radioactive waste disposal in rock salt – Leaching experiments and thermodynamic simulations

3. Complexation of Nd(III) with tetraborate ion and its effect on actinide(III) solubility in WIPP brine

4. Recent Advances in Aqueous Actinide Chemistry and Thermodynamics

5. R. Guillaumont , J.Fanghänel, V.Neck, J.Fuger, D. A.Palmer, I.Grenthe and M. H.Rand, Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, Chemical Thermodynamics, OECD, NEA-TDB, Elsevier, North Holland, Amsterdam, 2003, vol. 5

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