Initiating abilities of diphosphine- and diamine-ligated Pd complexes/NaBPh<sub>4</sub> systems for C1 polymerization of diazoacetates-Reference-Cited by-同舟云学术

Initiating abilities of diphosphine- and diamine-ligated Pd complexes/NaBPh₄ systems for C1 polymerization of diazoacetates

Published:2023 Issue:9 Volume:14 Page:1007-1018
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Shimomoto Hiroaki¹^ORCID,Miyano Yuto¹,Kinoshita Kaito¹,Itoh Tomomichi¹^ORCID,Ihara Eiji¹^ORCID

Affiliation:

1. Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama 790-8577, Japan

Abstract

(Diamine)Pd(0)(dichlone)/NaBPh4 systems have been revealed to be effective initiators for diazoacetate polymerization, yielding moderately syndiotactic polymers in moderate yields.

Funder

Iketani Science and Technology Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/2023/PY/D2PY01548J

Reference38 articles.

1. Poly(substituted Methylene) Synthesis: Construction of C–C Main Chain from One Carbon Unit

2. C1 polymerisation and related C–C bond forming ‘carbeneinsertion’ reactions