A salicylaldiminate/Pd(trifluoroacetate)<sub>2</sub> [SalAld/Pd(tfa)<sub>2</sub>] initiating system for C1 polymerization of diazoacetate: generation of an active initiator from ordinary reagents with facile procedures-Reference-Cited by-同舟云学术

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A salicylaldiminate/Pd(trifluoroacetate)₂ [SalAld/Pd(tfa)₂] initiating system for C1 polymerization of diazoacetate: generation of an active initiator from ordinary reagents with facile procedures

Published:2024 Issue:11 Volume:15 Page:1077-1084
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Shimomoto Hiroaki¹^ORCID,Izumoto Takaya¹,Yamashita Kazuki¹,Itoh Tomomichi¹^ORCID,Ihara Eiji¹^ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama 790-8577, Japan

Abstract

SalAld/Pd(tfa)2 initiating systems have been revealed to be effective for C1 polymerization of diazoacetate, yielding moderately syndiotactic polymers with high Mn in moderate yield.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D3PY01426F

Reference53 articles.

1. Polyhomologation. A Living C1 Polymerization

2. C1 polymerization: a unique tool towards polyethylene-based complex macromolecular architectures

3. Poly(substituted Methylene) Synthesis: Construction of C–C Main Chain from One Carbon Unit

4. C1 polymerisation and related C–C bond forming ‘carbeneinsertion’ reactions

5. Carbene insertion into transition metal–carbon bonds: a new tool for catalytic C–C bond formation

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