An unprecedented N- to C-sulfonyl migration in the reaction of azomethine amine and allenoates: access to arylsulfonylmethyl substituted pyrazolo[1,5-c]quinazoline and mechanistic studies

Author:

Ansari Arshad J.1234ORCID,Wani Aabid Abdullah56784,Maurya Antim K.910114,Verma Sarika1213144,Agnihotri Vijai K.910114ORCID,Sharon Ashoke1213144ORCID,Bharatam Prasad V.56784ORCID,Sawant Devesh M.1234ORCID

Affiliation:

1. School of Chemical Sciences and Pharmacy

2. Central University of Rajasthan

3. Ajmer-305817 (Raj)

4. India

5. Department of Medicinal Chemistry

6. National Institute of Pharmaceutical Education and Research

7. NIPER

8. S.A.S. Nagar (Mohali) – 160062

9. Natural Product Chemistry and Process Development Division

10. CSIR-IHBT

11. Palampur

12. Department of Chemistry

13. Birla Institute of Technology

14. Ranchi

Abstract

A serendipitous discovery of [1,3]-sulfonyl migration has been made in the two-component reaction of azomethine imine and allenoates.

Funder

Science and Engineering Research Board

Indian Council of Medical Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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