Efficient β-alkylation of secondary alcohols to α-substituted ketones catalyzed by functionalized Ir complexes <i>via</i> borrowing hydrogen in water-Reference-Cited by-同舟云学术

Efficient β-alkylation of secondary alcohols to α-substituted ketones catalyzed by functionalized Ir complexes via borrowing hydrogen in water

Published:2023 Issue:2 Volume:10 Page:355-362
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Xin¹²,Dong Wen-Zhe¹²,Li Yang¹²^ORCID,Yu Xiaoqiang²,Wang Wan-Hui¹²^ORCID,Himeda Yuichiro³^ORCID,Bao Ming¹²^ORCID

Affiliation:

1. School of Chemical Engineering, Dalian University of Technology, Liaodongwan New District, Panjin, China

2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Ganjingzi District, Dalian, China

3. National Institute of Advanced Industrial Science and Technology, Tsukuba, Japan

Abstract

Highly efficient and selective alkylation via borrowing hydrogen in water was achieved with a functional Ir complex bearing an amidate ligand. The significant cooperation effect of the ligand on the high efficiency and selectivity was demonstrated.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Liaoning Revitalization Talents Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01541B

Reference47 articles.

1. Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

2. Recent Advances in α-Alkylation Reactions using Alcohols with Hydrogen Borrowing Methodologies

3. C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation

4. Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis

5. Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals

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