Synthesis of Ir(iii) complexes with TpMe2 and acac ligands and their reactivity with electrophiles

Author:

Morales-Cerón Judith P.1234,Salazar-Pereda Verónica1234,Mendoza-Espinosa Daniel5674,Alvarado-Rodríguez José G.1234,Cruz-Borbolla Julián1234,Andrade-López Noemí1234,Vásquez-Pérez José M.12348

Affiliation:

1. Área Académica de Química

2. Universidad Autónoma del Estado de Hidalgo

3. Hidalgo

4. México

5. Departamento de Ciencias Básicas

6. Universidad Autónoma Metropolitana-Azcapotzalco

7. México D.F.

8. CONACyT

Abstract

Reaction of 1 with an excess of 2,4-pentanedione produced a mixture of complexes (6), (7) and (8). Complex 6 was treated with electrophiles yielding the substituted products in good yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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