CH bond activation in aromatic ketones mediated by iridium-tris(pyrazolyl)borate complexes-Reference-Cited by-同舟云学术

CH bond activation in aromatic ketones mediated by iridium-tris(pyrazolyl)borate complexes

Published:2023 Issue:48 Volume:52 Page:18315-18322
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ortiz-Hernández M.¹,Salazar-Pereda V.¹^ORCID,Mendoza-Espinosa D.¹^ORCID,Gomez-Bonilla M. A.¹,Cristobal C.²^ORCID,Ortega-Alfaro M. C.³^ORCID,Suárez A.⁴^ORCID,Sandoval-Chavez C. I.³

Affiliation:

1. Área Académica de Química, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km. 4.5, Mineral de la Reforma, Hidalgo, 42090, Mexico

2. Departamento de Química, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, Campus Noria Alta, Guanajuato, 36050, Mexico

3. Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Cuidad Universitaria, Alcaldía Coyoacán, 04510, Mexico

4. Instituto de Investigaciones Químicas, Departamento de Química Inorgánica, CSIC-Universidad de Sevilla, Avda. Américo Vespucio 49, 41092, Sevilla, Spain

Abstract

Reaction of complex [TpMe2Ir(η4-CH2C(Me)C(Me)C2)] (1) with a series of aromatic ketones at 130 °C renders, by means of a selective ortho-CH activation, Ir(iii)-metallacycles 2–5, which display an Ir–H bond.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02849F

Reference83 articles.

1. Catalytic asymmetric CH activation of sp3 hybridized CH bonds by means of carbenoid CH insertions: applications in organic synthesis

2. Catalytic C−H/Olefin Coupling

3. Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

4. Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by Cï£¿H Bond Cleavage

5. Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

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