Truncated conjugation in fused heterocycle-based conducting polymers: when greater planarity does not enhance conjugation-Reference-Cited by-同舟云学术

Truncated conjugation in fused heterocycle-based conducting polymers: when greater planarity does not enhance conjugation

Published:2023 Issue:4 Volume:14 Page:812-821
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Marin-Beloqui Jose Manuel¹²^ORCID,Gómez Sandra³^ORCID,Gonev Hristo Ivov¹^ORCID,Comí Marc⁴^ORCID,Al-Hashimi Mohammed⁴^ORCID,Clarke Tracey M.¹^ORCID

Affiliation:

1. Department of Chemistry, University College London, Christopher Ingold Building, London WC1H 0AJ, UK

2. Department of Physical Chemistry, University of Malaga, Blvrd Louis Pasteur 31, 29010, Malaga, Spain

3. Department of Physical Chemistry, University of Salamanca, Caidos Sq., 37008, Salamanca, Spain

4. Department of Chemistry, Texas A&M University at Qatar, Education City, P. O. Box 23874, Doha, Qatar

Abstract

A Raman spectroscopy and theoretical study to find an unconventional structure-property relationship. A larger planarity forms an alternative truncated conjugation pathway that hinders the beneficial a-conjugation selenophene pathway.

Funder

Qatar National Research Fund

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06271B

Reference63 articles.

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4. Design and synthesis of new ultra-low band gap thiadiazoloquinoxaline-based polymers for near-infrared organic photovoltaic application

5. An electron rich indaceno [2,1-b:6,5-b′] dithiophene derivative as a high intramolecular charge transfer material in dye sensitized solar cells

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