Selective ring-rearrangement or ring-closing metathesis of bicyclo[3.2.1]octenes

Author:

Semenova Evgeniya1234,Lahtigui Ouidad1234,Scott Sarah K.1234,Albritton Matthew1234,Abboud Khalil A.1234,Ghiviriga Ion1234,Roitberg Adrian E.1234,Grenning Alexander J.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Florida

3. Gainesville

4. USA

Abstract

Explored was the competitive ring-closing metathesis vs. ring-rearrangement metathesis of bicyclo[3.2.1]octenes prepared by a simple and convergent synthesis from bicyclic alkylidenemalononitriles and allylic electrophiles.

Funder

National Science Foundation

College of Liberal Arts and Sciences, University of Florida

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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