Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile-Reference-Cited by-同舟云学术

Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile

Published:2016 Issue:37 Volume:45 Page:14719-14724
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Holmsen Marte Sofie Martinsen¹²³⁴,Nova Ainara⁵¹²³⁴,Balcells David⁵¹²³⁴,Langseth Eirin¹²³⁴,Øien-Ødegaard Sigurd¹²³⁴,Tråseth Eline Aasen¹²³⁴,Heyn Richard H.⁶⁷⁴,Tilset Mats¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University of Oslo

3. N-0315 Oslo

4. Norway

5. Centre for Theoretical and Computational Chemistry (CTCC)

6. SINTEF Materials and Chemistry

7. N-0314 Oslo

Abstract

Incorporation of the simple, readily available, building blocks ethylene, water and acetonitrile into Au(tpy)(OCOCF₃)₂ (tpy = 2-(p-tolyl)pyridine) in a one-step reaction leads to high yields of a new 6-membered ring gold(iii) metallacycle complex.

Funder

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01648K

Reference40 articles.

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2. Gold-Catalyzed Benzylic CH Activation at Room Temperature

3. Modern Gold Catalyzed Synthesis, ed. A. S. K. Hashmi and F. D. Toste, Wiley-VCH, Weinheim, 2012