Installation of the adamantyl group in polystyrene-<i>block</i>-poly(methyl methacrylate) <i>via</i> Friedel–Crafts alkylation to modulate the microphase-separated morphology and dimensions-Reference-Cited by-同舟云学术

Installation of the adamantyl group in polystyrene-block-poly(methyl methacrylate) via Friedel–Crafts alkylation to modulate the microphase-separated morphology and dimensions

Published:2023 Issue:22 Volume:14 Page:2675-2684
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Isono Takuya¹^ORCID,Baba Ema²,Tanaka Shunma²,Miyagi Ken³,Dazai Takahiro³,Li Feng¹^ORCID,Yamamoto Takuya¹^ORCID,Tajima Kenji¹^ORCID,Satoh Toshifumi¹^ORCID

Affiliation:

1. Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan

2. Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan

3. Lithography Process Materials Research Group, R&D Department, Tokyo Ohka Kogyo Co., Ltd, Kanagawa 253-0114, Japan

Abstract

We present the polystyrene block post-polymerization modification of PS-b-PMMA through Friedel–Crafts alkylation with adamantanols to modulate its microphase-separated morphology and dimensions.

Funder

Hokkaido University

Creative Research Institute, Hokkaido University

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2023/PY/D3PY00113J

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