Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals-Reference-Cited by-同舟云学术

Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

Published:2015 Issue:73 Volume:51 Page:13925-13928
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Du Xiaoqiang¹²³⁴⁵,Ding Yong¹²³⁴⁵,Song Fangyuan¹²³⁴⁵,Ma Baochun¹²³⁴⁵,Zhao Junwei⁶⁷⁸⁹¹⁰,Song Jie¹¹¹²¹³¹⁴

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry

2. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province

3. and College of Chemistry and Chemical Engineering

4. Lanzhou University

5. Lanzhou 730000

6. Henan Key Laboratory of Polyoxometalate Chemistry

7. College of Chemistry and Chemical Engineering

8. Henan University

9. Kaifeng

10. P. R. China

11. Department of Biomedical Engineering

12. Emory University and Georgia Institute of Technology

13. Atlanta

14. USA

Abstract

We report a novel molecular polyanionic cluster of eleven-Fe^III substituted antimoniotungstate Na₂₇[Fe₁₁(H₂O)₁₄(OH)₂(W₃O₁₀)₂(α-SbW₉O₃₃)₆]·103H₂O (1). Under optimal conditions, a turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOF_initial) of 6.3 s⁻¹ over 1 were achieved for water oxidation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04551G

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