Scandium-catalyzed chemoselective carbene insertion into N–H over S–H: access to <i>o</i>-alkylamine-diaryl disulfides-Reference-Cited by-同舟云学术

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Scandium-catalyzed chemoselective carbene insertion into N–H over S–H: access to o-alkylamine-diaryl disulfides

Published:2024 Issue:28 Volume:60 Page:3798-3801
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sun Haoyany¹^ORCID,Pan Junhong¹,Zhao Wenying¹,Zhou Tong¹,Song Xizhong²³,Lin Jun¹^ORCID,Jin Yi¹³^ORCID

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education; Yunnan Key Laboratory of Research & Development for Natural Products; School of Pharmacy, Yunnan University, Kunming, 650091, P.R. China

2. State Key Laboratory of Southwestern Chinese Medicine Resources, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137, P.R. China

3. Jiangxi Fangzhu Pharmaceutical Co., Ltd, Xinyu 338000, P.R. China

Abstract

A Sc-catalyzed chemoselective carbene insertion into N–H bond over S–H bond. The first example of the synthesis of o-alkylamine-diaryl disulfides through the N-alkylation of o-aminobenzenethiol, also undergoing oxidative coupling to form S–S bond.

Funder

National Natural Science Foundation of China

Double Thousand Plan of Jiangxi Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00557K

Reference30 articles.

1. Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

2. Catalytic X–H insertion reactions based on carbenoids

3. Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

4. Enzymatic Nitrogen Insertion into Unactivated C–H Bonds

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