Recent advances in transition-metal-catalyzed carbene insertion to C

Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

Published:2022 Issue:7 Volume:51 Page:2759-2852
ISSN:0306-0012
Container-title:Chemical Society Reviews
language:en
Short-container-title:Chem. Soc. Rev.

Author:

He Yuan¹²^ORCID,Huang Zilong¹²^ORCID,Wu Kaikai¹^ORCID,Ma Juan¹²^ORCID,Zhou Yong-Gui¹^ORCID,Yu Zhengkun¹³⁴^ORCID

Affiliation:

1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, P. R. China

2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China

4. Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

This review summarizes the recent advance in transition-metal-catalyzed carbene insertion to C–H bonds, forming diverse C–C bonds.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CS/D1CS00895A

Reference496 articles.

1. 3d Transition Metals for C–H Activation

2. Pd-Catalyzed ipso,meta-Dimethylation of ortho-Substituted Iodoarenes via a Base-Controlled C–H Activation Cascade with Dimethyl Carbonate as the Methyl Source

3. Palladium‐Catalyzed Silacyclization of (Hetero)Arenes with a Tetrasilane Reagent through Twofold C−H Activation

4. Recent Advances in Asymmetric Catalytic Metal Carbene Transformations

5. Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

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