Localized vibration and avoided crossing in SrTi11O20 for oxide thermoelectrics with intrinsically low thermal conductivity

Author:

Li Yi12345ORCID,Yamamoto Shinya678910,Ahmad Kaleem1112131415,Almutairi Zeyad1112131415ORCID,Koumoto Kunihito1617101819,Wan Chunlei12345ORCID

Affiliation:

1. State Key Laboratory of New Ceramics and Fine Processing

2. School of Materials Science and Engineering

3. Tsinghua University

4. Beijing 100084

5. P. R. China

6. Department of Applied Chemistry

7. Graduate School of Engineering

8. Nagoya University

9. Nagoya 464-8603

10. Japan

11. Sustainable Energy Technologies Center

12. College of Engineering

13. King Saud University

14. Riyadh

15. Saudi Arabia

16. Nagoya Industrial Science Research Institute

17. Nagoya 464-0819

18. Center of Nanotechnology

19. King Abdulaziz University

Abstract

The localized vibration in SrTi11O20 forms low-lying optical phonon bands that distort acoustic phonon branches through the avoided crossing effect. The electrical and thermal transport are decoupled to achieve phonon-glass electron-crystal behaviour.

Funder

Tsinghua University

Ministry of Education – Kingdom of Saudi Arabi

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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