Enantioselective carbolithiation of S-alkenyl-N-aryl thiocarbamates: kinetic and thermodynamic control-Reference-Cited by-同舟云学术

Enantioselective carbolithiation of S-alkenyl-N-aryl thiocarbamates: kinetic and thermodynamic control

Published:2015 Issue:8 Volume:13 Page:2330-2340
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Castagnolo Daniele¹²³⁴,Degennaro Leonardo⁵⁶⁷,Luisi Renzo⁵⁶⁷,Clayden Jonathan¹²³⁴

Affiliation:

1. School of Chemistry

2. University of Manchester

3. Manchester M13 9PL

4. UK

5. Department of Pharmacy – Drug Sciences University of Bari “A. Moro”

6. 70125 Bari

7. Italy

Abstract

Carbolithiation of vinyl thiocarbamates may proceed with the same sense of enantioselectivity with either (−)-sparteine and (+)-sparteine surrogate ligands.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02329C

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