Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization

Author:

Perfetti Mauro1234ORCID,Gysler Maren1234,Rechkemmer-Patalen Yvonne1234,Zhang Peng1234ORCID,Taştan Hatice1234,Fischer Florian1234,Netz Julia1234,Frey Wolfgang5234,Zimmermann Lucas W.6234,Schleid Thomas6234,Hakl Michael7891011,Orlita Milan7891011,Ungur Liviu12131415ORCID,Chibotaru Liviu12131415,Brock-Nannestad Theis161718,Piligkos Stergios161718ORCID,van Slageren Joris1234ORCID

Affiliation:

1. Institut für Physikalische Chemie

2. Universität Stuttgart

3. D-70569 Stuttgart

4. Germany

5. Institut für Organische Chemie

6. Institut für Anorganische Chemie

7. Laboratoire National des Champs Magnétiques Intenses (LNCMI-EMFL)

8. CNRS

9. UGA

10. 38042 Grenoble

11. France

12. Theory of Nanomaterials Group

13. Katholieke Universiteit Leuven

14. 3001 Leuven

15. Belgium

16. Department of Chemistry

17. University of Copenhagen

18. Denmark

Abstract

We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule magnet [Dy2(bpm)(fod)6] (Hfod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2-bipyrimidine).

Funder

Alexander von Humboldt-Stiftung

European Cooperation in Science and Technology

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference84 articles.

1. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

2. Lanthanide Single-Molecule Magnets

3. Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

4. S.-D. Jiang , B.-W.Wang and S.Gao , in Molecular Nanomagnets and Related Phenomena , ed. S. Gao , Springer Berlin Heidelberg , Berlin, Heidelberg , 2015 , pp. 111–141

5. Lanthanides and Actinides in Molecular Magnetism , ed. R. Layfield and M. Murugesu , Wiley-VCH , Weinheim , 2015

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