Cyclopentyl methyl ether as a green solvent for reversible-addition fragmentation chain transfer and nitroxide-mediated polymerizations

Author:

Abreu Carlos M. R.12345,Maximiano Pedro12345,Guliashvili Tamaz67,Nicolas Julien89101112,Serra Arménio C.12345ORCID,Coelho Jorge F. J.12345ORCID

Affiliation:

1. CEMUC

2. Department of Chemical Engineering

3. University of Coimbra

4. 3030-790 Coimbra

5. Portugal

6. Cytosorbents Inc.

7. USA

8. Institut Galien Paris-Sud

9. CNRS UMR 8612

10. Univ Paris-Sud

11. Faculté de Pharmacie

12. Châtenay-Malabry cedex

Abstract

Cyclopentyl methyl ether (CPME) was successfully used as an environmentally friendly alternative to regularly employed organic solvents (e.g., THF, DMSO, DCM and DMF) for the RAFT and NMP polymerizations of vinyl chloride (VC) and styrene (S).

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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