A trinuclear nickel(ii) Schiff base complex with phenoxido- and acetato-bridges: combined experimental and theoretical magneto-structural correlation

Author:

Thakurta Santarupa1234ORCID,Maiti Monami1564,Butcher Ray J.1789ORCID,Gómez-García Carlos J.10111213ORCID,Tsaturyan Arshak A.141516171ORCID

Affiliation:

1. Department of Chemistry

2. Prabhu Jagatbandhu College

3. Howrah 711302

4. India

5. Narasinha Dutt College

6. Howrah 711101

7. Howard University

8. Washington

9. USA

10. Department of Inorganic Chemistry

11. Institute of Molecular Science (ICMol)

12. 46980 Paterna

13. Spain

14. Institute of Physical and Organic Chemistry

15. Southern Federal University

16. 344090 Rostov-on-Don

17. Russian Federation

Abstract

A new Ni(ii) trimer with single-phenoxido and acetato bridges has been prepared and structurally characterized. Magnetic measurements and theoretical calculations allow to establish a magneto-structural correlation for this kind of bridges.

Funder

Ministerio de Economía y Competitividad

Generalitat Valenciana

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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