Vapor-triggered reversible crystal transformation of a nickel-based magnetic molecular switch

Author:

Xue Shufang1,Solre Gideon F. B.1ORCID,Wang Xiaoqin1,Wang Liang1,Guo Yunnan1ORCID

Affiliation:

1. Department of Chemistry, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China

Abstract

Vapor-triggered crystal-to-crystal transformation between a discrete trinuclear complex [Ni3(sih)2(py)8] and a two-dimensional (2D) coordination polymer [Ni3(sih)2(py)2]n·2DMF·2H2O was demonstrated, showing a solid-state coordination-induced spin state switch behavior.

Funder

Zhejiang Sci-Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference48 articles.

1. Bistable molecular materials with dynamic structures

2. Spin-state switches in molecular materials chemistry

3. A.Danilov and S.Kubatkin , in Handbook of Single-Molecule Electronics , ed. K. Moth-Poulsen , Jenny Stanford Publishing , New York , 2015 , ch. 9, p. 263

4. Molecular Magnetic Switches

5. 90-degree optical switching of output second-harmonic light in chiral photomagnet

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