Six-coordinate ferric porphyrins containing bidentate N-t-butyl-N-nitrosohydroxylaminato ligands: structure, magnetism, IR spectroelectrochemisty, and reactivity

Author:

Xu Nan12345,Christian Jonathan H.1674,Dalal Naresh S.1674,Abucayon Erwin G.1234,Lingafelt Colin584,Powell Douglas R.1234,Richter-Addo George B.1234

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Oklahoma

3. Norman

4. USA

5. Division of Mathematics and Natural Sciences

6. Florida State University

7. Tallahassee

8. Altoona

Abstract

Protonation of iron porphyrin NONOates generates N2O via the intermediacy of HNO. Reactions with imidazole results in N–N bond cleavage to yield RNO and NO.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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