CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template

Author:

Wang Tongdao1234,Wang Long1234,Daniliuc Constantin G.1234,Samigullin Kamil5674,Wagner Matthias5674,Kehr Gerald1234ORCID,Erker Gerhard1234ORCID

Affiliation:

1. Organisch-Chemisches Institut

2. Westfälische Wilhelms-Universität Münster

3. 48149 Münster

4. Germany

5. Institut für Anorganische und Analytische Chemie

6. Goethe-Universität Frankfurt

7. 60438 Frankfurt am Main

Abstract

The reversible enamine/HB(C6F5)2 Lewis adduct reacts with CO by selective head to tail coupling whereas it reacts with NO via a vicinal N/B Lewis pair to give a head to head NO/NO coupling product.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference88 articles.

1. Frustrated Lewis Pair Chemistry: Development and Perspectives

2. Frustrated Lewis Pairs I, Uncovering and Understanding, Top. Curr. Chem., ed. G. Erker and D. W. Stephan, Heidelberg, 2013, vol. 332

3. Frustrated Lewis Pairs II, Expanding the Scope, Top. Curr. Chem., ed. G. Erker and D. W. Stephan, Heidelberg, 2013, vol. 334

4. Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

5. Carbonylation Reactions of Intramolecular Vicinal Frustrated Phosphane/Borane Lewis Pairs

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