Reactivation from the Ni–B state in [NiFe] hydrogenase of Ralstonia eutropha is controlled by reduction of the superoxidised proximal cluster-Reference-Cited by-同舟云学术

Reactivation from the Ni–B state in [NiFe] hydrogenase of Ralstonia eutropha is controlled by reduction of the superoxidised proximal cluster

Published:2016 Issue:12 Volume:52 Page:2632-2635
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Radu Valentin¹²³⁴⁵,Frielingsdorf Stefan⁶⁷⁸⁹¹⁰,Lenz Oliver⁶⁷⁸⁹¹⁰,Jeuken Lars J. C.¹²³⁴⁵

Affiliation:

1. School of Biomedical Sciences

2. The Astbury Centre for Structural Molecular Biology

3. University of Leeds

4. Leeds LS2 9JT

5. UK

6. Institut für Chemie

7. Sekretariat PC14

8. Technische Universität Berlin

9. 10623 Berlin

10. Germany

Abstract

The tolerance towards oxic conditions of O₂-tolerant [NiFe] hydrogenases has been attributed to an unusual [4Fe–3S] cluster that lies proximal to the [NiFe] active site.

Funder

European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC10382G

Reference39 articles.

1. Hydrogenases

2. Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalystElectronic supplementary information (ESI) available: Levich plots at 1% and 10% hydrogen, and a comparison of the effect of carbon monoxide on oxidation currents obtained at platinum and enzyme-modified electrodes. See http://www.rsc.org/suppdata/cc/b2/b201337a/

3. Dynamic electrochemical investigations of hydrogen oxidation and production by enzymes and implications for future technology

4. Occurrence, Classification, and Biological Function of Hydrogenases: An Overview

5. [FeFe]-Hydrogenase-Catalyzed H2 Production in a Photoelectrochemical Biofuel Cell

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