Why surface hydrophobicity promotes CO<sub>2</sub> electroreduction: a case study of hydrophobic polymer <i>N</i>-heterocyclic carbenes-Reference-Cited by-全球学者库

Why surface hydrophobicity promotes CO₂ electroreduction: a case study of hydrophobic polymer N-heterocyclic carbenes

Published:2023 Issue:36 Volume:14 Page:9664-9677
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Luo Qiang¹^ORCID,Duan Hanyi²^ORCID,McLaughlin Michael C.¹,Wei Kecheng³,Tapia Joseph⁴,Adewuyi Joseph A.¹,Shuster Seth¹,Liaqat Maham¹,Suib Steven L.¹^ORCID,Ung Gaël¹^ORCID,Bai Peng⁴^ORCID,Sun Shouheng³^ORCID,He Jie¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Connecticut, Storrs, CT 06269, USA

2. Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA

3. Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA

4. Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003, USA

Abstract

Polymer NHCs as a strong binding motif together with hydrophobicity control the accessibility of substrates at catalyst–electrolyte interface and enhance CO2 electroreduction on metal catalysts.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02658B

Reference73 articles.

1. Electrochemical Reduction of CO2 Catalyzed by Metal Nanocatalysts

2. Hybrid Catalyst Coupling Single-Atom Ni and Nanoscale Cu for Efficient CO₂ Electroreduction to Ethylene

3. Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products

4. Boosting CO 2 Electrochemical Reduction with Atomically Precise Surface Modification on Gold Nanoclusters

5. Dissecting Critical Factors for Electrochemical CO ₂ Reduction on Atomically Precise Au Nanoclusters

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