Symmetry-breaking charge separation in a nitrogen-bridged naphthalene monoimide dimer-Reference-Cited by-同舟云学术

Symmetry-breaking charge separation in a nitrogen-bridged naphthalene monoimide dimer

Published:2022 Issue:22 Volume:24 Page:14007-14015
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Niu Xinmiao¹²³,Tajima Keita⁴,Kong Jie²³^ORCID,Tao Min²³,Fukui Norihito⁴^ORCID,Kuang Zhuoran¹,Shinokubo Hiroshi⁴^ORCID,Xia Andong¹³^ORCID

Affiliation:

1. State Key Laboratory of Information Photonic and Optical Communications, School of Science, Beijing University of Posts and Telecommunications (BUPT), Beijing 100176, P. R. China

2. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

4. Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan

Abstract

The model molecule, bis-ANI (consisting of two naphthalimide moieties) was studied to better understand the process of charge separation. It is found that the central amino linker facilitates the formation of a charge separation state in bis-ANI.

Funder

National Natural Science Foundation of China

Beijing University of Posts and Telecommunications

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00295G

Reference58 articles.

1. Excited-State Symmetry Breaking in Cofacial and Linear Dimers of a Green Perylenediimide Chlorophyll Analogue Leading to Ultrafast Charge Separation