Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes-Reference-Cited by-同舟云学术

Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

Published:2018 Issue:50 Volume:54 Page:6808-6811
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yruegas Sam¹²³⁴,Martinez Jesse J.¹²³⁴,Martin Caleb D.¹²³⁴^ORCID

Affiliation:

1. Baylor University

2. Department of Chemistry and Biochemistry

3. Waco

4. USA

Abstract

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N₂ or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC01529E

Reference61 articles.

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4. Boron–nitrogen- and boron-substituted anthracenes and -phenanthrenes as models for doped carbon-based materials

5. Fused polycyclic aromatics incorporating boron in the core: fundamentals and applications

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