Pd-Oxazolone complexes conjugated to an engineered enzyme: improving fluorescence and catalytic properties

Author:

Garcia-Sanz Carla1234,Andreu Alicia1234,de las Rivas Blanca56784,Jimenez Ana I.910114ORCID,Pop Alexandra1213141516ORCID,Silvestru Cristian1213141516ORCID,Urriolabeitia Esteban P.910114ORCID,Palomo Jose M.1234ORCID

Affiliation:

1. Department of Biocatalysis

2. Institute of Catalysis (ICP-CSIC)

3. 28049 Madrid

4. Spain

5. Department of Microbial Biotechnology

6. Institute of Food Science

7. Technology and Nutrition (ICTAN-CSIC)

8. 28040 Madrid

9. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

10. CSIC-Universidad de Zaragoza

11. 50009 Zaragoza

12. Supramolecular Organic and Organometallic Chemistry Centre

13. Department of Chemistry

14. Babeş-Bolyai University

15. RO-400028 Cluj-Napoca

16. Romania

Abstract

A very mild and selective approach to greatly improved properties of Pd oxazolones by site-incorporation on an enzyme is reported. The new Pd–enzyme conjugates were fluorescents at ppm concentrations and excellent catalysts in different reactions.

Funder

Consejo Superior de Investigaciones Científicas

European Cooperation in Science and Technology

Ministry of Education and Research, Romania

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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