Orthopalladated imidazolones and thiazolones: synthesis, photophysical properties and photochemical reactivity

Author:

Dumitraş Darius1ORCID,Dalmau David2ORCID,García-Orduña Pilar2ORCID,Pop Alexandra1ORCID,Silvestru Anca1ORCID,Urriolabeitia Esteban P.2ORCID

Affiliation:

1. Supramolecular Organic and Organometallic Chemistry Centre, Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Arany Janos 11, 400028 Cluj-Napoca, Romania

2. Instituto de Síntesis Química y Catálisis Homogénea, ISQCH, CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009, Zaragoza, Spain

Abstract

The incorporation of Pd into the molecular framework of 4-arylidene-imidazolones or thiazolones generates platforms with remarkable photophysical and photochemical properties. Quantum yields of up to 15% and a clear photoreactivity have been achieved.

Funder

Agencia Estatal de Investigación

Gobierno de Aragón

Universitatea Babeş-Bolyai

Publisher

Royal Society of Chemistry (RSC)

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