Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms-Reference-Cited by-同舟云学术

Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms

Published:2021 Issue:1 Volume:57 Page:125-128
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fernández-Moyano Sara¹²³⁴⁵^ORCID,Peñas-Defrutos Marconi N.¹²³⁴⁵^ORCID,Bartolomé Camino¹²³⁴⁵^ORCID,Espinet Pablo¹²³⁴⁵^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica

2. Facultad de Ciencias

3. Universidad de Valladolid

4. Valladolid-47071

5. Spain

Abstract

A striking and puzzling unreported Ar/Cl scrambling in Au(iii) turns out to have an interesting mechanistic explanation.

Funder

Ministerio de Economía y Competitividad

Ministerio de Educación, Cultura y Deporte

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC06450E

Reference28 articles.

1. A. Luquin , E.Cerrada and M.Laguna , in Gold Chemistry: Applications and Future Directions in the Life Sciences , ed. Mohr, F. , Wiley-VCH , Weinheim , 2009 , ch. 3, pp 93–181

2. S. Coco and P.Espinet , Gold Chemistry , ch. 8, pp 357–396

3. Metal-Induced Phosphorescence in (Pentafluorophenyl)gold(III) Complexes

4. Harnessing White‐Light Luminescence via Tunable Singlet‐and Triplet‐Derived Emissions Based on Gold(III) Complexes *

5. Stable N-heterocyclic carbene (NHC) cyclometalated (C^C) gold(iii) complexes as blue–blue green phosphorescence emitters

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