Abstract
In this paper, we describe a series of diphenylphosphane and diphenylphosphanide gold(III) and gold(III)/gold(I) complexes containing 3,5-C6Cl2F3 as aryl ligands at gold that have been synthesized due to the arylating and oxidant properties of the new polymeric thallium(III) complex [TlCl(3,5-C6Cl2F3)2]n (1). Its reaction with [Au(3,5-C6Cl2F3)(tht)] (tht = tetrahydrothiophene) produces the gold(III) complex [Au(3,5-C6Cl2F3)3(tht)] (2), which allows the synthesis of the diphenylohosphane derivative [Au(3,5-C6Cl2F3)3(PPh2H)] (3). Its treatment with acetylacetonate gold(I) derivatives leads to two novel AuIII/AuI phosphanido-bridged complexes, [PPN][Au(3,5-C6Cl2F3)3(µ-PPh2)AuCl] (4) and [PPN][{(3,5-C6Cl2F3)3Au(µ-PPh2)}2Au] (5). All these complexes have been characterized, and the crystal structures of 1, 2, 4 and 5 have been established by single crystal X-ray diffraction methods, showing a novel polymeric arrangement in 1.
Funder
Spanish D.G.I. MINECO/FEDER
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Reference52 articles.
1. Sidgwick, N.V. (1927). The Electronic Theory of Valency, Clarendon Press.
2. Perfluoroarylgold complexes;Laguna;Coord. Chem. Rev.,2008
3. Downs, A.J. (1993). Chemistry of Aluminium, Gallium, Indium and Thallium, Blackie Academic and Professional.
4. Structural aspects of the coordination chemistry of organothallium(III) and organomercury(II) derivatives;Casas;Coord. Chem. Rev.,1999
5. Synthesis and characterization of pentachlorophenyl-metal derivatives with d0 and d10 electron configurations;Ara;Chem. Eur. J.,2004
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献