Two-electron/24-center (2e/24c) bonding in novel diradical π-dimers-Reference-Cited by-同舟云学术

Two-electron/24-center (2e/24c) bonding in novel diradical π-dimers

Published:2016 Issue:42 Volume:18 Page:29041-29044
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gao Feng-Wei¹²³⁴⁵,Zhong Rong-Lin¹²³⁴⁵,Sun Shi-Ling¹²³⁴⁵,Xu Hong-Liang¹²³⁴⁵,Su Zhong-Min¹²³⁴⁵

Affiliation:

1. The Institute of Functional Material Chemistry

2. National & Local United Engineering Laboratory for Power Batteries

3. Northeast Normal University

4. Changchun

5. China

Abstract

A whole new pancake-shaped 2e/24c π–π bonding is presented in diradical π-dimers 2 due to combination of twelve p–π interactions. Among these new radical π-dimers 2, the 2180 shows the smallest layer distance and the largest interaction between two layers of radicals.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP05410B

Reference37 articles.

1. Is There a Lower Limit to the CC Bonding Distances in Neutral Radical π-Dimers? The Case of Phenalenyl Derivatives

2. Hybrid Density Functional Theory Studies on the Magnetic Interactions and the Weak Covalent Bonding for the Phenalenyl Radical Dimeric Pair

3. Aromaticity on the Pancake-Bonded Dimer of Neutral Phenalenyl Radical as Studied by MS and NMR Spectroscopies and NICS Analysis

4. The Tetracyanopyrazinide Dimer Dianion, [TCNP]22−. 2-Electron 8-Center Bonding

5. Comparative Analysis of the Multicenter, Long Bond in [TCNE]·− and Phenalenyl Radical Dimers: A Unified Description of Multicenter, Long Bonds

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