Comparative Analysis of the Multicenter, Long Bond in [TCNE]·− and Phenalenyl Radical Dimers: A Unified Description of Multicenter, Long Bonds
Author:
Affiliation:
1. Departament de Química Física & IQTCUB Facultat de Química, Universitat de Barcelona, Avenida Diagonal, 647, 08028-Barcelona, Spain, and Department of Chemistry, University of Utah, Salt Lake City, Utah 84112-0850
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9002298
Reference41 articles.
1. Exceptionally Long (≥2.9 Å) C−C Bonds between [TCNE]− Ions: Two-Electron, Four-Center π*-π* C−C Bonding in π-[TCNE]22−
2. Exceptionally Long (≥2.9 Å) CC Bonding Interactions in π-[TCNE]22 Dimers: Two-Electron Four-Center Cation-Mediated CC Bonding Interactions Involving π* Electrons
3. On the existence of long C–C bonds between pairs of anions which repel: when and why? A test case on the [TCNE]22−dimers found in ionic crystals
4. Four-Center Carbon−Carbon Bonding
5. A Stable Neutral Hydrocarbon Radical: Synthesis, Crystal Structure, and Physical Properties of 2,5,8-Tri-tert-butyl-phenalenyl
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