Inelastic neutron scattering: a novel approach towards determination of equilibrium isotopic fractionation factors. Size effects on heat capacity and beta-factor of diamond-Reference-Cited by-同舟云学术

Inelastic neutron scattering: a novel approach towards determination of equilibrium isotopic fractionation factors. Size effects on heat capacity and beta-factor of diamond

Published:2020 Issue:23 Volume:22 Page:13261-13270
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Shiryaev Andrey A.¹²³^ORCID,Polyakov Veniamin B.⁴⁵³^ORCID,Rols Stephane⁶⁷⁸,Rivera Antonio⁹¹⁰¹¹¹²¹³,Shenderova Olga¹⁴¹⁵¹⁶

Affiliation:

1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS

2. Moscow

3. Russia

4. D.S. Korzhinskii Institute of Experimental Mineralogy RAS

5. Chernogolovka

6. Institut Laue-Langevin

7. 38042 Grenoble

8. France

9. Instituto de Fusión Nuclear

10. Dep. Ingeniería Energética

11. ETSI Industriales

12. Universidad Politécnica de Madrid

13. Spain

14. Adámas Nanotechnologies

15. Raleigh

16. USA

Abstract

Inelastic neutron scattering is a novel method for determination of thermodynamic and isotopic properties of nanoparticles. Influence of surface can be evaluated. The C_v of nanodiamonds is higher and the β-factor is lower than those of bulk diamond.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02032J

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