Magnetic behavior and ground spin states for coordination {L·[MII(Hal)2]3}3− assemblies (Hal = Cl or I) of radical trianion hexacyanohexaazatriphenylenes (L) with three coordinated high-spin FeII (S = 2) or CoII (S = 3/2) centers-Reference-Cited by-同舟云学术

Magnetic behavior and ground spin states for coordination {L·[M^II(Hal)₂]₃}³⁻ assemblies (Hal = Cl or I) of radical trianion hexacyanohexaazatriphenylenes (L) with three coordinated high-spin Fe^II (S = 2) or Co^II (S = 3/2) centers

Published:2023 Issue:32 Volume:52 Page:11222-11233
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mikhailenko Maxim V.¹,Ivanov Vladislav V.¹²,Shestakov Alexander F.¹²,Kuzmin Aleksey V.³,Khasanov Salavat S.³,Otsuka Akihiro⁴^ORCID,Yamochi Hideki⁴^ORCID,Kitagawa Hiroshi⁴^ORCID,Konarev Dmitri V.¹^ORCID

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow region, 142432, Russia

2. Moscow State University, Leninskie Gory, Moscow, 119991 Russia

3. Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432 Russia

4. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

Abstract

A series of trianion assemblies with hexaazatriphenylenehexacarbonitrile {HAT(CN)6} and hexaazatrinaphthylenehexacarbonitrile {HATNA(CN)6} with Fe(ii) or Co(ii) ions are obtained. Parameters affecting the magnetic properties of the assemblies are discussed.

Funder

Russian Science Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01571H

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