Manganese(<scp>ii</scp>) complexes of hexaazatrinaphthylene and hexaazatrianthracene: synthesis, structure and properties-Reference-Cited by-同舟云学术

Manganese(ii) complexes of hexaazatrinaphthylene and hexaazatrianthracene: synthesis, structure and properties

Published:2023 Issue:48 Volume:47 Page:22339-22349
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mikhailenko Maxim V.¹,Ivanov Vladislav V.¹,Faraonov Maxim A.¹^ORCID,Kuzmin Aleksey V.²,Khasanov Salavat S.²,Otsuka Akihiro³^ORCID,Yamochi Hideki³^ORCID,Kitagawa Hiroshi³^ORCID,Konarev Dmitri V.¹^ORCID

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow region, 142432, Russia

2. Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432, Russia

3. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

Abstract

A series of complexes containing dianionic and radical-trianionic hexaazatriphenylene (HATNA) and hexazatrianthracene (HATA) ligands and high-spin MnII ions (S = 5/2) were obtained. It is shown that elongation of the Mn–N bonds results in a decrease of both Mn–ligand and Mn–Mn couplings.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ04615J

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