Effects of coordinating heteroatoms on molecular structure, thermodynamic stability and redox behavior of uranyl(<scp>vi</scp>) complexes with pentadentate Schiff-base ligands-Reference-Cited by-同舟云学术

Effects of coordinating heteroatoms on molecular structure, thermodynamic stability and redox behavior of uranyl(vi) complexes with pentadentate Schiff-base ligands

Published:2022 Issue:37 Volume:12 Page:24260-24268
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Takeyama Tomoyuki¹^ORCID,Takao Koichiro¹^ORCID

Affiliation:

1. Laboratory for Zero-Carbon Energy, Institute of Innovative Research, Tokyo Institute of Technology, 2-12-1 N1-32, O-Okayama, Meguro-ku, Tokyo 152-8550, Japan

Abstract

The U–X bond strength and thermodynamic stability of uranyl(vi) complexes with pentadentate N2O2X1-donating ligands (X = NH, O, S) are affected by the difference in X. In contrast, the X atom does not largely affect the redox behavior of the complexes.

Funder

Japan Society for the Promotion of Science

Japan Atomic Energy Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA04639C

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