Utility of redox-active ligands for reversible multi-electron transfer in uranyl(<scp>vi</scp>) complexes-Reference-Cited by-同舟云学术

Utility of redox-active ligands for reversible multi-electron transfer in uranyl(vi) complexes

Published:2023 Issue:14 Volume:10 Page:4028-4044
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Takeyama Tomoyuki¹^ORCID,Tsushima Satoru²³^ORCID,Takao Koichiro¹^ORCID

Affiliation:

1. Laboratory for Zero-Carbon Energy, Institute of Innovative Research, Tokyo Institute of Technology N1-32, 2-12-1, Ookayama, Meguro-ku, 152-8550 Tokyo, Japan

2. Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany

3. International Research Frontiers Initiative (IRFI), Institute of Innovative Research, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8550 Tokyo, Japan

Abstract

Three uranyl(vi) complexes with redox-active ligands showed reversible multi-step redox processes. Their redox centers are always the coordinating ligand and the centered U exhibits redox-innocent behavior.

Funder

Japan Society for the Promotion of Science

Tokyo Institute of Technology

Japan Atomic Energy Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI00189J

Reference79 articles.

1. Noninnocence in Metal Complexes: A Dithiolene Dawn